Researchers at Doshisha University in Japan have created a new method to transform agricultural waste into a copper-enhanced material that can effectively remove synthetic dyes from industrial wastewater. The project was led by Asif Ali, a Ph.D. student and MEXT scholar, along with professors Michiaki Matsumoto and Yoshiro Tahara from the university's Department of Applied Chemistry. The findings were published in the Journal of Environmental Chemical Engineering.
Synthetic dyes are commonly found in wastewater from industries like textile manufacturing, paper production, leather processing, and food processing. These dyes are chemically stable, hard to break down, and can persist in the environment, posing risks to aquatic ecosystems and human health. According to Ali, about 20% of toxic, hard-to-treat textile wastewater is discharged without proper treatment, causing significant harm to both aquatic life and human health. Traditional methods for treating this kind of wastewater, such as membrane separation and advanced oxidation, can be expensive and energy-intensive. While activated carbon is a good alternative, it can be costly to produce and reuse. Some methods that use metals to improve performance require additional chemicals for the process.
To address these issues, the research team used bullrush, a type of agricultural waste, as a sustainable source of carbon. They used copper(II) nitrate trihydrate and potassium hydroxide (KOH) to grow copper nanoparticles within a porous structure of the material. The team employed a single-step process called co-pyrolysis, which used naturally occurring gases from the bullrush (carbon monoxide and hydrogen) to reduce copper compounds without adding extra chemicals. This produced a composite material called ZVCu@BAC, which contains copper nanoparticles embedded in activated carbon derived from bullrush.
Tests showed that ZVCu@BAC was highly effective at removing both cationic dyes like methylene blue and anionic dyes like methyl orange and sunset yellow. The material maintained its performance even after multiple uses and could be regenerated using a solution of potassium hydroxide and acetone. The cost of producing the composite is estimated to be about ¥1,800 per kilogram. The material's ability to handle a wide range of pH levels and its potential for repeated use make it a promising option for treating industrial wastewater. The study suggests that this composite could be a sustainable, cost-effective, and scalable solution for cleaning water in industrial settings.
Professor Matsumoto highlighted the importance of the research, noting that it offers a way to turn invasive bullrush, which is often considered a weed, into a valuable resource. By using an eco-friendly, single-step process, the team has taken a significant step toward protecting water resources and promoting a circular economy, where waste is minimized and resources are reused. The research could bring us closer to keeping rivers and streams clean and ensuring the sustainability of water treatment processes.
Agricultural waste transformed into copper-enhanced material for dye removal from industrial wastewater
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Original sources:
- 🇺🇸Phys.org



